X. Peter Zhang

X. Peter Zhang is a Professor in the Department of Chemistry at Boston College, where he leads a research group focused on innovative catalytic methodologies. His work bridges fundamental organometallic chemistry and practical synthetic applications, with a strong emphasis on stereoselective transformations.

Education:

• Ph.D., University of Pennsylvania
• NIH Postdoctoral Fellowship

Dr. Zhang's research centers on the development of Metalloradical Catalysis (MRC), a paradigm that enables control over reactivity and selectivity in radical processes. His group specializes in Co(II)-based chiral porphyrin catalysts, which facilitate enantioselective radical reactions such as C–H amination, cyclopropanation, and cyclization. These methods leverage unique intermediates like α-metalloalkyl and α-metalloaminyl radicals, offering solutions to longstanding synthetic challenges.

The recent publications (2017–2021) demonstrate a consistent trend in asymmetric radical chemistry, particularly in C–H functionalization and ring formation. The work spans from catalyst design to mechanistic studies, with applications in the synthesis of biologically relevant scaffolds such as cyclic sulfonamides and cyclopropyl amino acids. The research is highly interdisciplinary, intersecting organic, inorganic, and physical organic chemistry.

Scientific Awards:

• NSF CAREER Award (2006)
• ORAU Ralph Powe Faculty Award (2003)
• NIH Postdoctoral Fellowship (1996)

Dr. Zhang has secured significant recognition and funding, reflecting the impact of his research. His group actively trains graduate students and postdoctoral researchers, contributing to the next generation of synthetic chemists. While student names are not listed, his advising role is evident through co-authorship patterns. There is no mention of specific grants, but prestigious awards like the NSF CAREER suggest sustained federal support.

The research is conducted through a dedicated laboratory at the Merkert Center, utilizing advanced spectroscopic and synthetic techniques to explore metalloradical mechanisms and develop new transformations.